Biomineralization can lead to produce different phases of CaCO 3 anhydrous polymorphs such as calcite, aragonite and vaterite, as well as hydrated crystalline phases such as monohydrocalcite (CaCO 3 ·H 2 O) and hexahydrocalcite or ikaite (CaCO 3 ·6H 2 O) and amorphous calcium carbonate (ACC) (Krumbein 1979; Hammes et al. 2003a; Wei et al. 2003; Ben Chekroun et al. 2004; Xu et al. 2006; Chen
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